煤粉锅炉脱硫系统中除尘器压差过高原因及解决方案

高倍率灰钙循环烟气脱硫技术在神东矿区的煤粉锅炉环保改造项目中已投入建设并成功运行,脱硫率可达95%以上。在NGD系统的运行调试期,布袋除尘器压差的数值及其上升速度均较改造前有大幅提高,影响了锅炉系统的正常运行并降低了布袋除尘器的运行效率。为了解决此问题,先分析滤料透气性降低而导致布袋除尘器压差上升的根本原因,再结合现场调研情况对NGD系统工况下的烟气含湿量、烟气温度、烟气灰浓度、除尘器本体的问题以及上游锅炉系统问题逐一进行对比和分析,并找出问题产生的各主要因素。NGD系统中布袋除尘器差压升高的原因包括多方面,为了使NGD系统的运行更加稳定,需要使除尘器适应NGD系统的工况并对系统中部分设备进行改造。在未来NGD系统的设计中,布袋除尘器需按高浓度烟气设计,且针对煤粉工业锅炉的运行、维护特性应加入对烟气中含水量的监测及对布袋除尘器的相应保护措施。     

Impact of inorganic waste fines on structure of mullite microspheres by reaction sintering

The impact of waste composition and morphology on the properties of the mullite microstructure were studied by reaction sintering two types of siliceous waste powders with calcined alum sludge. Stoichiometric mixtures of fly ash or rice husk ash with the alum sludge were shaped into mullite microspheres by droplet coagulation. The mullitization reaction was followed by HT-XRD with a distinct difference in onset temperature. The specific powder composition of fly ash (presence of primary mullite) shifted the onset temperature to higher values as compared to the rice husk ash mixture. After sintering at 1600?°C, the mullitization reaction resulted in the same yield for both samples. Although the mullite content in the microspheres was equal, distinct differences on the microstructure could be observed. Reaction sintering of the fly ash mixture resulted in lower total porosity with smaller pore sizes.     

EB-PVD alumina (Al2O3) as a top coat on 7YSZ TBCs against CMAS/VA infiltration: Deposition and reaction mechanisms

Al₂O₃ was deposited as a top coat on a standard 7YSZ layer (or layers) by means of EB-PVD technique and the corresponding morphology of the Al₂O₃/7YSZ coatings was studied in detail. This multi-layer TBC system was tested against calcium-magnesium-aluminium-silicate (CMAS) recession by performing infiltration experiments for different time intervals from 5?min to 50?h at 1250?°C using two types of synthetic CMAS compositions and Eyjafjallajökull volcanic ash (VA) from Iceland. The results show that the studied EB-PVD Al₂O₃/7YSZ coatings react quickly with CMAS or VA melt and form crystalline spinel (MgAl_2-xFe_xO₄) and anorthite (CaAl₂Si₂O₄) phases. The presence of Fe-oxide in the CMAS has been found to be key element in influencing the spinel formation which was proved to be more efficient against CMAS sealing in comparison to the Fe-free CMAS compositions. Even though a rapid crystallization was assured, shrinkage cracks in the EB-PVD alumina layer produced during the crystallization heat treatment have proven to be detrimental for the CMAS/VA infiltration resistance. To overcome these microstructural drawbacks, an additional alumina deposition method, namely reaction-bonded alumina oxide (RBAO), was applied on top of EB-PVD Al₂O_3. RBAO acts as a sacrificial layer forming stable reaction products inhibiting further infiltration.     

煤矿工业场地道路照明接地系统问题探讨

文章简要介绍了煤矿工业场地的特点和低压配电系统接地方式分类,从安全性、经济性的角度分析了TN接地系统和TT接地系统在道路照明回路中的优缺点。通过对比TN-S系统与TT系统的接地故障电流差异、TN-S接地系统用于道路照明的等电位联结困难程度,总结出煤矿工业场地的道路照明配电系统适宜采用TT接地方式。并且详细阐述了TT接地系统剩余电流动作保护器保护整定方法和灵敏度校验方法,列举了煤矿工业场地道路照明选用TT系统时需要注意的中性线不可重复接地的问题。     

黔西南某中高硫煤脱硫过程中微量元素的分配特性研究

为探究黔西南某中高硫煤中微量元素的富集程度,以及在脱硫降灰提质利用过程中微量元素的分配特性,通过摇床对其脱硫降灰进行了试验研究,并在合适的分选工艺条件下,考察了原煤、精煤和尾煤产品中微量元素的分配特征。通过“一粗一精一扫”重选,可获得产率32.83%、硫分0.96%、灰分11.16%的合格精煤产品。分选产品微量元素分析结果表明,该分选工艺对Cu、Sb、As、Co、Mo、TI、Ni等有害元素具有较好的脱除效果,并能一定程度富集锂和稀土等有价微量元素。通过此工艺可分别回收28.73%和47.37%的锂至精煤和中煤产品,精煤煤灰中Li₂O理论含量达5 258 μg/g,具有综合回收利用价值。研究结果可为该类中高硫煤炭资源的清洁与综合利用提供参考。     

Ionic liquids for coal dissolution,extraction and liquefaction

Coal is the most abundant fossil fuel. Direct combustion of low- and medium-rank coals causes alarming environmental impacts. Therefore, it is crucial for coal to undergo pretreatments before its efficient utilization [such as coal to liquid (CTL) processes]. Conventional pretreatment methods suffer from several limitations including the use of volatile organic solvents, environmental hazards, strong reaction conditions (e.g. high temperature and pressure), consumption of large quantities of nonrecoverable chemicals (e.g. bases used in aqueous alkaline digestion), or being only effective for specific coals. On the other hand, coal pretreatment by nonvolatile ionic liquids (ILs) could lead to partial coal dissolution/swelling and structure disruption, which is a critical step before coal liquefaction, hydrogenation, pyrolysis or the inhibition of oxidation/combustion. In addition, ILs are suitable solvents for extracting sulfur compounds from coal, asphaltenes from Direct Coal Liquefaction Residues (DCLR) and phenolic compounds from coal tar. This review will discuss these aspects of coal pretreatments by ILs, and identify how ILs could lead to a cleaner and more efficient utilization of coal resources. © 2020 Society of Chemical Industry     

综采工作面过上覆煤柱技术研究

近距离上层煤开采过后留有许多残余煤柱,这些煤柱往往导致下层煤开采过程中出现强烈的矿压显现情况。针对综采工作面过上覆采空区煤柱矿压显现剧烈的问题,以山西上榆泉煤矿工作面地质条件为基础,对相邻43303工作面回采过程中的矿压显现情况进行了总结分析,确定上层煤煤柱与本层煤顶板形成的次生顶板结构是造成工作面来压强度增大的主要原因,并从43302工作面过上覆煤柱前、中、后三个阶段,制定了改变采高、调斜、顶板预裂以及加快工作面推进速度等技术措施。根据现场实践效果,采用该措施能够减弱工作面矿压显现强度,改善工作面片帮、冒顶等情况,实现对工作面降压的目的,具有良好的应用效果。     

智能化救援监控系统在煤矿安全生产中的应用

针对煤矿发生事故后传统救援监控系统无法实时对井下人员进行动态定位，导致矿井救援盲目性大、救援效率差、救援难度大等技术难题，为了进一步提高煤矿救援效率，通过技术研究，设计了一套以通信基站为核心的智能化救援监控系统，分析了该系统结构组成、工作原理，通过在担水沟煤矿井下实际应用效果来看，智能化救援监控系统对人员定位精准度达95%，实现人员动态位置三维成像，救援效率提高至80%以上，有效缩短了煤矿事故救援时间，取得了显著应用成效。     

昌图西部地区地层及赋煤情况分析

通过对昌图西部地区尤其以古榆、付家为中心的区域以往几十年的勘探地质资料进行整理,总结昌图西部地区含煤情况。对该区域内煤炭资源潜力及成矿地质单元进行分析,对含煤地层进行整理对比,对未来该地区找煤提供良好的标识。     

煤红外快速热解过程中床层对二次反应的影响

针对煤快速热解研究中样品添加量少(mg级)、焦油收集难等问题，本研究利用压片法制备微薄厚度(mm级)的煤层，并采用红外加热装置考察大添加量(g级)、微薄煤层的快速热解特性。对比堆积煤样和不同煤压片厚度(1.5~3 mm)与个数(1~2)的压片煤样热解特性发现，压片煤层热解过程的二次反应受到明显抑制，焦油产率急剧增加，在1000℃时达9.96%，为格金分析的1.5倍，实现油气产量的同步增长。模拟蒸馏分析发现，堆积状态下焦油以沥青质为主，而微薄煤层制焦油含大量轻油、酚油、萘油、洗油和蒽油。GC-MS和FTIR分析表明，随煤层厚度和个数的减少，焦油组分和含量提高，芳香烃类和含氧官能团吸收增加，进一步验证煤快速热解过程中煤层厚度对焦油产率和品质的影响，揭示在二次反应充分抑制下煤高温热解的初级反应特性。